Synthesis, Evaluation, Modeling and Simulation of Nanopore NaA Zeolite Membranes for Application in Ethanol Separation

  • Mansoor Kazemimoghadam Malek-Ashtar University of Technology
  • Zahra Amiri Rigi Islamic Azad University
Keywords: nanopores, pervaporation, ethanol separation, zeolite NaA membrane, FEM simulation

Abstract

Zeolite membranes have uniform and molecular-sized pores that separate molecules based on the differences in the molecules’ adsorption and diffusion properties. Strong electrostatic interaction between ionic sites and water molecules (due to its highly polar nature) makes the zeolite NaA membrane very hydrophilic. Zeolite NaA membranes are thus well suited for the separation of liquid-phase mixtures by pervaporation. In this study, experiments were conducted with various ethanol–water mixtures (1–20 wt. %) at 25 °C. Total flux for ethanol–water mixtures was found to vary from 0.331 to 0.229 kg/m2.h with increasing thanol concentration from 1 to 20 wt.%. Ionic sites of the NaA zeolite matrix play a very important role in water transport through the membrane. These sites act both as water sorption and transport sites. Surface diffusion of water occurs in an activated fashion through these sites. The precise Nano-porous structure of the zeolite cage helps in a partial molecular sieving of the large solvent molecules leading to high separation factors. A comparison between experimental flux and calculated flux using Stephan Maxwell (S.M.) correlation was made and a linear trend was found to exist for water flux through the membrane with ethanol concentration. A comprehensive model also was proposed for the ethanol-water pervaporation by Finite Element Method (FEM). The 2D model was masterfully capable of predicting water concentration distribution within both the membrane and the feed side of the pervaporation membrane module.

Keywords: nanopores, pervaporation, ethanol separation, zeolite NaA membrane, FEM simulation

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Published
2018-06-20
How to Cite
Kazemimoghadam, M., & Rigi, Z. (2018). Synthesis, Evaluation, Modeling and Simulation of Nanopore NaA Zeolite Membranes for Application in Ethanol Separation. Journal of Applied Chemical Sciences, 5(2), 445-458. Retrieved from http://ejurnal.undana.ac.id/jacs/article/view/2005

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