Use of Polymer Membranes for Modeling Desulfurization in the Process of Pervaporation through Artificial Neural Network
Abstract
The present study considered the amount of thiophene_alkane separation within the process of pervaporation by use of-of membrane polyethylene glycol and polydimethylsiloxane-polyacrylonitrile with the help of Artificial Neural Network Modeling. In this research, the effects of such parameters as Volumetric flow rate and temperature, as well as feedstuff properties (separation factor and flux) on the Desulfurization process efficiency were evaluated, and the Multi Layers Perceptron (MLP) neural network feed forward along with Propagation learning algorithm and Levenberg-Marquardt function with inputs and outputs were implemented. Tansig activation algorithm was used for the hidden layer, and Purelin algorithm was utilized for the output layer. Furthermore, 5 neurons were defined for the hidden layer. After processing the data, 70 percent were allocated for learning, 15% were allocated for validity, and the remaining 15% was allocated for the experience. The achieved results with the aforementioned method had a suitable accuracy. The graphs of the error percentage for the actual values of the separation factor and flux outputs were compared to the achieved values from modeling through related membranes for evaluating the efficiency of pervaporation process in a separation of ethanol, Acetone, and butanol from the water. Finally, the graphs were drawn.
Keywords: Modeling, desulfurization, artificial neural networks, polyethylene glycol
Downloads
References
2. Mulder M. Basic Principles of Membrane Technology. Springer Netherlands; 1996. DOI:10.1007/978-94-009-1766-8
3. Qi R, Wang Y, Chen J, Li J, Zhu S. Pervaporative desulfurization of model gasoline with Ag2O-filled PDMS membranes. S. 2007;57(1):170-175. DOI:10.1016/j.seppur.2007.04.001
4. Rautenbach R, Albrecht R. The separation potential of pervaporation. J. 1985;25(1):1-23. DOI:10.1016/s0376-7388(00)83001-x
5. Shokir EME-M, Alsughayer AA, Al-Ateeq A. Permeability Estimation From Well Log Responses. Journal of Canadian Petroleum Technology. 2006;45(11). DOI:10.2118/06-11-05
6. Wang J, Guo Q, Zhang C, Li K. One-pot extractive and oxidative desulfurization of liquid fuels with molecular oxygen in ionic liquids. R. 2014;4(104):59885-59889. DOI:10.1039/c4ra09659b
7. Al-Shahrani F, Xiao T, Llewellyn SA, et al. Desulfurization of diesel via the H2O2 oxidation of aromatic sulfides to sulfones using a tungstate catalyst. A. 2007;73(3-4):311-316. DOI:10.1016/j.apcatb.2006.12.016
8. Bösmann A, Datsevich L, Jess A, Lauter A, Schmitz C, Wasserscheid P. C. 2001;(23):2494-2495. DOI:10.1039/b108411a
9. Dooley KM, Liu D, Madrid AM, Knopf FC. Oxidative desulfurization of diesel with oxygen: Reaction pathways on supported metal and metal oxide catalysts. A. 2013;468:143-149. DOI:10.1016/j.apcata.2013.08.013
10. Goda HM, Maier H, Behrenbruch P. The Development of an Optimal Artificial Neural Network Model for Estimating Initial Water Saturation – Australian Reservoir. In: SPE Asia Pacific Oil and Gas Conference and Exhibition. Society of Petroleum Engineers; 2005. DOI:10.2118/93307-ms
11. Huang C, Chen B, Zhang J, Liu Z, Li Y. Desulfurization of Gasoline by Extraction with New Ionic Liquids. E. 2004;18(6):1862-1864. DOI:10.1021/ef049879k
12. Lin L, Kong Y, Wang G, Qu H, Yang J, Shi D. Selection and crosslinking modification of membrane material for FCC gasoline desulfurization. J. 2006;285(1-2):144-151. DOI:10.1016/j.memsci.2006.08.016
13. Lin L, Kong Y, Yang J, Shi D, Xie K, Zhang Y. Scale-up of pervaporation for gasoline desulphurization. J. 2007;298(1-2):1-13. DOI:10.1016/j.memsci.2007.03.052
14. Maier HR, Dandy GC. Neural networks for the prediction and forecasting of water resources variables: a review of modelling issues and applications. E. 2000;15(1):101-124. DOI:10.1016/s1364-8152(99)00007-9
15. Shahab M. Virtual-Intelligence Applications in Petroleum Engineering: Part 1—Artificial Neural Networks. J. 2000;52(9). DOI:10.2118/58046-ms
16. Yazu K, Makino M, Ukegawa K. Oxidative Desulfurization of Diesel Oil with Hydrogen Peroxide in the Presence of Acid Catalyst in Diesel Oil/Acetic Acid Biphasic System. C. 2004;33(10):1306-1307. DOI:10.1246/cl.2004.1306
Copyright (c) 2019 Journal of Applied Chemical Sciences
This work is licensed under a Creative Commons Attribution-NonCommercial-ShareAlike 4.0 International License.