Synthesis and Characterization of Zeolite from Refractory Brick Waste

  • Odi Th. E. Selan(1*)
  • Maria D. Hema(2)
  • Fredy Z. Saudale(3)
  • Suwari Suwari(4)
  • (*) Corresponding Author
Keywords: Brick, zeolite, natrolite, silicate, aluminate, material

Abstract

The synthesis of zeolite from refractory brick waste using hydrothermal technique had been conducted. Two different reactans, NaOH and Mg(OH)2, were separately employed to react with SiO2 and Al2O3 from brick sample to produce metal silicate and metal aluminate which were then reacted to obtain zeolite. XRF results show that the synthesized products using both reactants have Si/Al ratios between 1-1.5 considered as low type of zeolites regardless some remaining impurities.  XRD data reveal a typical pattern of zeolite with 2 Ɵ angles of 15.91; 19.52; 25.47; 32.20; 35.54 and 41.54.  The IR vibration characteristic of Si-O and Al-O bonds appears in 454 cm-1 while the symmetric and asymmetric stretching vibrations of these two bonds absorb around 679.66 – 778.02 cm-1 and 2033.96-1092.42 cm-1, respectively. The O-H group from Si-OH associated with the formation of zeolite gives a characteristic feature at 3618 cm-1. SEM analysis also shows similar morphological features with natrolite zeolite. The use of NaOH as reactant gives more zeolite product compared to Mg(OH)2 reactant.

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References

1 Yaseen M, H PM, Bandlekar RM, M SR, R PS, R S V et al. Strength Characteristics Of Ecofriendly Cement Bricks Using Solid Waste Composites. 2018; 4.www.ijsart.com.
2 Cobîrzan N, Balog A-A, Thalmaier G, Nasui M, Munteanu C, Babota F. Microscopical and Macroscopical Analysis of Recovered Bricks for Assessing Their Reusability in Masonry Buildings. Procedia Manuf 2020; 46: 144–149.
3 Lourenço PB, Fernandes FM, Castro F. Handmade clay bricks: Chemical, physical and mechanical properties. Int J Archit Herit 2010; 4: 38–58.
4 Mohiuddin E, Isa YM, Mdleleni MM, Sincadu N, Key D, Tshabalala T. Synthesis of ZSM-5 from impure and beneficiated Grahamstown kaolin: Effect of kaolinite content, crystallisation temperatures and time. Appl Clay Sci 2016; 119: 213–221.
5 Orjioke NM. Synthesis and Characterization of Zeolite and Its Application in Adsorption of Nickel from Aqueous Solution. J Pharm Chem Biol Sci 2015; 3: 592–600.
6 Said NF, Widiastuti N. ADSORPSI Cu ( II ) PADA ZEOLIT A YANG DISINTESIS DARI ABU DASAR BATUBARA PT IPMOMI PAITON. J Zeolit Indones 2008; 7: 1–11.
7 Nurhayati ND, Wigiani A. Sintetis Katalis Ni-Cr/Zeolit dengan Metode Impregnasi Terpisah. Semin Nas Kim dan Pendidik Kim VI 2014; : 479–484.
8 Sarwar S, Ko KW, Han J, Han CH, Jun Y, Hong S. Improved Long-term Stability of Dye-Sensitized Solar Cell by Zeolite Additive in Electrolyte. Electrochim Acta 2017; 245: 526–530.
9 Tirta Indah Wulan Sari, Muhsin HW. Pengaruh Metode Aktivasi pada Kemampuan Kaolin Sebagai Adsorben Besi (Fe) Air Sumur Garuda. Konversi 2016; 5: 20–25.
10 Zhao SX, Ta N, Wang XD. Effect of temperature on the structural and physicochemical properties of biochar with apple tree branches as feedstock material. Energies 2017; 10. doi:10.3390/en10091293.
11 Lestari DY. Kajian Modifikasi dan Karakterisasi Zeolit Alam dari Berbagai Negara. Pros Semin Nas Kim dan Pendidik Kim 2010 2010; : 6.
12 Dan PC, Dengan N, Sio P. PEMANFAATAN Cu-NaA DAN NaA DENGAN PREKURSOR SiO 2 DARI SEKAM PADI UNTUK ADSORPSI GAS NO. 2011; 1.
13 Franzoni E, Pigino B, Leemann A, Lura P. Use of TEOS for fired-clay bricks consolidation. Mater Struct Constr 2014; 47: 1175–1184.
14 Charlena, Henny Purwaningsih TR. Pencirian dan Uji Aktivitas Katalitik Zeolite Alam Teraktivasi. J Ris Kim 2008; 1: 107–115.
15 Aloulou H, Bouhamed H, Ghorbel A, Amar R Ben, Khemakhem S. Elaboration and characterization of ceramic microfiltration membranes from natural zeolite: Application to the treatment of cuttlefish effluents. Desalin Water Treat 2017; 95: 9–17.
16 Peter Atkins, Tina Overton, Jonathan Rourke, Mark Weller, Fraser Armstrong MH. Shriver & Atkins’ Inorganic Chemistry. 5th ed. 2010 doi:10.1007/978-1-84628-986-6_2.
17 Saputra R. Pemanfaatan zeolit sintetis sebagai alternatif pengolahan limbah industri. J Hibah Bersaing 2006; 3: 1–8.
18 Ibrahim K. Mineralogy and chemistry of natrolite from Jordan. Clay Miner 2014; 39: 47–55.
19 Li HJ, Zhou XD, Zhang JM, Wu XY, Gao HB. The Preparation and Characterization of Natrolite Synthetized by Purified Attapulgite. IOP Conf Ser Mater Sci Eng 2017; 205. doi:10.1088/1757-899X/205/1/012030.
20 Kristiyani D, Susatyo E. B PAT. Pemanfaatan Zeolite Abu Sekam Padi untuk menurunkan kadar ion Pb2+ pada air sumur. Indones J Chem Sci 2012; 1: 13–19.
21 Nur H. Direct synthesis of NaA zeolite from rice husk and carbonaceous rice husk ash. Indones J Agric Sci 2001; 1: 40–45.

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Published
2021-06-30
How to Cite
Selan, O., Hema, M., Saudale, F., & Suwari, S. (2021). Synthesis and Characterization of Zeolite from Refractory Brick Waste. Chemistry Notes, 3((1), 12-20. https://doi.org/10.35508/cn.v3i(1).4733

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