Uji Stabilitas Polymer Inclusion Membrane dari Polimer Pendukung PVC, Ekstraktan D2EHPA, dan Plasticizer Asam Oleat pada Kondisi Asam
Stability Test of Polymer Inclusion Membrane Fabricated Using PVC as Base Polymer D2EHPA as Extractant and Oleic Acid as Plasticizer Under Acidic Condition
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William Antoni Rensini(1)
Program Studi Kimia, Fakultas Sains dan Teknik, Universitas Nusa Cendana, Jl. Adisucipto Penfui, Kupang, Nusa Tenggara Timur 85001
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Luther Kadang(2)
Program Studi Kimia, Fakultas Sains dan Teknik, Universitas Nusa Cendana, Jl. Adisucipto Penfui, Kupang, Nusa Tenggara Timur 85001
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Titus Lapailaka(3)
Program Studi Kimia, Fakultas Sains dan Teknik, Universitas Nusa Cendana, Jl. Adisucipto Penfui, Kupang, Nusa Tenggara Timur 85001
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Johnson Nune Naat(4)
Program Studi Pendidikan Kimia, Fakultas Keguruan dan Ilmu Pendidikan, Universitas Nusa Cendana, Jl. Adisucipto Penfui, Kupang, Nusa Tenggara Timur 85001
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Redi Kristian Pingak(5)
Program Studi Fisika, Fakultas Sains dan Teknik, Universitas Nusa Cendana, Jl. Adisucipto Penfui, Kupang, Nusa Tenggara Timur 85001
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Origenes Boy Kapitan(6)
Politeknik Pertanian Negeri Kupang, Jl. Prof. Dr. Herman Yohanes, Lasiana, Kec. Kelapa Lima, Kota Kupang, Nusa Tenggara Timur 85001
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Fidelis Nitti(7*)
Program Studi Kimia, Fakultas Sains dan Teknik, Universitas Nusa Cendana, Jl. Adisucipto Penfui, Kupang, Nusa Tenggara Timur 85001
(*) Corresponding Author
Abstract
Polymer Inclusion Membrane (PIM) merupakan membran cair generasi terbaru untuk pemisahan berbagai jenis komponen kimia organik dan anorganik. Stabilitas PIM merupakan faktor yang sangat penting untuk efektivitas pemisahan yang berkelanjutan. Penelitian ini dilakukan untuk menyelidiki kestabilan PIM yang dibuat dari PVC sebagai polimer pendukung, D2EHPA sebagai ekstraktan, dan asam oleat (AO) sebagai plasticizer dalam HCl 2,5 M. Hasil penelitian menunjukkan komposisi PIM optimum adalah 50% PVC, 40% D2EHPA, dan 10% AO yang menunjukkan karakteristik fisik yang ideal seperti tipis, transparan, fleksibel dengan permukaan yang tidak berminyak. Hasil penelitian menunjukkan penurunan berat PIM yang direndam dalam HCl 2,5 M lebih kecil dibandingkan dengan penurunan berat PIM yang direndam dalam air selama 7 hari. Hasil ini menunjukkan bahwa PIM lebih stabil dalam kondisi asam dibandingkan dalam air (netral). Perbandingan karakteristik kimia PIM sebelum dan setelah uji stabilitas menunjukkan PIM yang direndam dalam air mengalami kehilangan fase cair selama proses uji stabilitas. Perbedaan ini terkonfirmasi melalui perbedaan karakteristik fisika PIM sebelum dan sesudah uji stabilitas. Secara keseluruhan, PIM dengan komposisi optimum 50% PVC, 40% D2EHPA, dan 10% AO disarankan untuk digunakan dalam pemisahan pada kondisi asam untuk mempertahankan stabilitas dan efisiensi pemisahannya.
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Copyright (c) 2024 Fidelis Nitti, William Antoni Rensini, Titus Lapailaka, Luther Kadang, Redi Kristian Pingak, Origenes Boy Kapitan, Johnson Nune Naat
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